全文获取类型
收费全文 | 6342篇 |
免费 | 662篇 |
国内免费 | 355篇 |
专业分类
化学 | 409篇 |
晶体学 | 6篇 |
力学 | 568篇 |
综合类 | 147篇 |
数学 | 4355篇 |
物理学 | 1874篇 |
出版年
2024年 | 6篇 |
2023年 | 51篇 |
2022年 | 60篇 |
2021年 | 131篇 |
2020年 | 160篇 |
2019年 | 158篇 |
2018年 | 147篇 |
2017年 | 180篇 |
2016年 | 181篇 |
2015年 | 147篇 |
2014年 | 226篇 |
2013年 | 509篇 |
2012年 | 250篇 |
2011年 | 295篇 |
2010年 | 239篇 |
2009年 | 323篇 |
2008年 | 388篇 |
2007年 | 404篇 |
2006年 | 360篇 |
2005年 | 279篇 |
2004年 | 258篇 |
2003年 | 287篇 |
2002年 | 289篇 |
2001年 | 256篇 |
2000年 | 263篇 |
1999年 | 200篇 |
1998年 | 180篇 |
1997年 | 144篇 |
1996年 | 108篇 |
1995年 | 74篇 |
1994年 | 101篇 |
1993年 | 69篇 |
1992年 | 70篇 |
1991年 | 74篇 |
1990年 | 59篇 |
1989年 | 51篇 |
1988年 | 48篇 |
1987年 | 39篇 |
1986年 | 29篇 |
1985年 | 37篇 |
1984年 | 53篇 |
1983年 | 26篇 |
1982年 | 22篇 |
1981年 | 30篇 |
1980年 | 16篇 |
1979年 | 16篇 |
1978年 | 15篇 |
1977年 | 12篇 |
1976年 | 12篇 |
1973年 | 6篇 |
排序方式: 共有7359条查询结果,搜索用时 15 毫秒
1.
Renny Mathew Karolina A. Uchman Lydia Gkoura Chris J. Pickard Maria Baias 《Magnetic resonance in chemistry : MRC》2020,58(11):1018-1025
A combined experimental and computational approach was used to distinguish between different polymorphs of the pharmaceutical drug aspirin. This method involves the use of ab initio random structure searching (AIRSS), a density functional theory (DFT)-based crystal structure prediction method for the high-accuracy prediction of polymorphic structures, with DFT calculations of nuclear magnetic resonance (NMR) parameters and solid-state NMR experiments at natural abundance. AIRSS was used to predict the crystal structures of form-I and form-II of aspirin. The root-mean-square deviation between experimental and calculated 1H chemical shifts was used to identify form-I as the polymorph present in the experimental sample, the selection being successful despite the large similarities between the molecular environments in the crystals of the two polymorphs. 相似文献
2.
Second-order random wave solutions for interfacial internal waves in N-layer density-stratified fluid 下载免费PDF全文
This paper studies the random internal wave equations describing the density interface displacements and the velocity potentials of N-layer stratified fluid contained between two rigid walls at the top and bottom. The density interface displacements and the velocity potentials were solved to the second-order by an expansion approach used by Longuet-Higgins (1963) and Dean (1979) in the study of random surface waves and by Song (2004) in the study of second- order random wave solutions for internal waves in a two-layer fluid. The obtained results indicate that the first-order solutions are a linear superposition of many wave components with different amplitudes, wave numbers and frequencies, and that the amplitudes of first-order wave components with the same wave numbers and frequencies between the adjacent density interfaces are modulated by each other. They also show that the second-order solutions consist of two parts: the first one is the first-order solutions, and the second one is the solutions of the second-order asymptotic equations, which describe the second-order nonlinear modification and the second-order wave-wave interactions not only among the wave components on same density interfaces but also among the wave components between the adjacent density interfaces. Both the first-order and second-order solutions depend on the density and depth of each layer. It is also deduced that the results of the present work include those derived by Song (2004) for second-order random wave solutions for internal waves in a two-layer fluid as a particular case. 相似文献
3.
Jong Uhn Kim 《Transactions of the American Mathematical Society》2002,354(3):1117-1135
In this paper we discuss an initial-boundary value problem for a stochastic nonlinear equation arising in one-dimensional viscoelasticity. We propose to use a new direct method to obtain a solution. This method is expected to be applicable to a broad class of nonlinear stochastic partial differential equations.
4.
NA序列部分和的矩完全收敛性 总被引:4,自引:0,他引:4
讨论了NA序列部分和的矩完全收敛性,在一定条件下获得了NA序列矩完全收敛的充要条件,显示了矩完全收敛和矩条件之间的关系,将独立同分布随机变量序列矩完全收敛的结果推广到NA序列,得到了与独立随机变量序列情形类似的结果. 相似文献
5.
作为移位平面分拆的自然拓广,本文引入了梯形平面分拆的概念.应用矢量控制技巧,建立了给定形状和行(列)分部约束的列严格梯形平面分拆集合之枚举函数的初等对称函数行列式表达式.其中之一的重要特例构成了关于循环对称平面分拆的Macdonald猜想的证明基础. 相似文献
6.
T. Temesvári C. De Dominicis I.R. Pimentel 《The European Physical Journal B - Condensed Matter and Complex Systems》2002,25(3):361-372
Symmetry considerations and a direct, Hubbard-Stratonovich type, derivation are used to construct a replica field-theory relevant
to the study of the spin glass transition of short range models in a magnetic field. A mean-field treatment reveals that two
different types of transitions exist, whenever the replica number n is kept larger than zero. The Sherrington-Kirkpatrick critical point in zero magnetic field between the paramagnet and replica
magnet (a replica symmetric phase with a nonzero spin glass order parameter) separates from the de Almeida-Thouless line,
along which replica symmetry breaking occurs. We argue that for studying the de Almeida-Thouless transition around the upper
critical dimension d = 6, it is necessary to use the generic cubic model with all the three bare masses and eight cubic couplings. The critical
role n may play is also emphasized. To make perturbative calculations feasible, a new representation of the cubic interaction is
introduced. To illustrate the method, we compute the masses in one-loop order. Some technical details and a list of vertex
rules are presented to help future renormalisation-group calculations.
Received 9 October 2001 相似文献
7.
We analyze diffusion from a periodic array of hemispherical droplets through a membrane. We find that the multiple sources do not interact strongly, even when the droplets are closely spaced, so that the flux through the membrane appears nearly additive. 相似文献
8.
双向分束角对称的偏光分束镜设计与性能分析 总被引:4,自引:4,他引:0
为了获得分束角对称的偏光分束棱镜,在双Wollaston棱镜结构的基础上,通过合理设计棱镜左右两端晶体光轴的取向,使棱镜整体呈中心切面对称;在保证对正向入射的光对称分束的同时,对反向入射光同样可以对称分束,达到了双向对称分束的目的;在此基础上给出了晶体光轴的旋转角δ与棱镜结构角S以及与波长的关系;并分析了对633 nm设计的棱镜用于其他波长时分束角的对称性.结果表明:在±300 nm的光谱范围内,分束角的不对称度均小于0.24°. 相似文献
9.
给出2005年全国部分高校研究生数学建模竞赛D题的研究背景,对参赛论文作了简要评注,并提供了一种参考解答. 相似文献
10.
We obtain upper bounds for the tail distribution of the first nonnegative sum of a random walk and for the moments of the overshoot over an arbitrary nonnegative level if the expectation of jumps is positive and close to zero. In addition, we find an estimate for the expectation of the first ladder epoch. 相似文献